Chiral Selenide/Achiral Sulfonic Acid Cocatalyzed Atroposelective Sulfenylation of Biaryl Phenols via a Desymmetrization/Kinetic Resolution Sequence.
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DOI: 10.1021/jacs.1c09635
Abstract: Enantioselective synthesis of axially chiral sulfur-containing biaryl derivatives through the electrophilic sulfenylation of biaryl phenols has been achieved for the first time. This catalytic asymmetric system, which involves sequential desymmetrization and kinetic resolution, is enabled… read more here.
Keywords: achiral sulfonic; biaryl; desymmetrization kinetic; sulfenylation biaryl ... See more keywords