Desymmetrization of Vicinal Bis(boronic) Esters by Enantioselective Suzuki-Miyaura Cross-Coupling Reaction.
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DOI: 10.1021/jacs.3c01571
Abstract: The development of an enantioselective catalytic Suzuki-Miyaura reaction that applies to meso 1,2-diborylcycloalkanes is described. This reaction provides a modular route to enantiomerically enriched substituted carbocycles and heterocycles that retain a synthetically versatile boronic ester.… read more here.
Keywords: reaction; boronic esters; suzuki miyaura; desymmetrization vicinal ... See more keywords