Convenient Synthesis of Deuterosilanes by Direct H/D Exchange Mediated by Easily Accessible Pt(0) Complexes
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DOI: 10.1021/acsomega.6b00401
Abstract: Easily accessible, simple phosphino-platinum(0) complexes catalyze (0.1–1 mol % equivalent) the deuteration of silanes in good yields under mild conditions (60 °C, 1 atm). The catalysis is mediated by platinum(II) deuteride/hydride complexes that are in… read more here.
Keywords: exchange mediated; direct exchange; easily accessible; deuterosilanes direct ... See more keywords