Development of Chiral, Bifunctional Thiosquaramides: Enantioselective Michael Additions of Barbituric Acids to Nitroalkenes.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b01115
Abstract: We report a general method for the synthesis of chiral thiosquaramides, a class of bifunctional catalysts not previously described in the literature. Thiosquaramides are found to be more acidic and significantly more soluble in nonpolar… read more here.
Keywords: thiosquaramides enantioselective; chiral bifunctional; enantioselective michael; bifunctional thiosquaramides ... See more keywords
The development of chiral metal–organic frameworks for enantioseparation of racemates
Sign Up to like & getrecommendations! Published in 2023 at "RSC Advances"
DOI: 10.1039/d3ra02489j
Abstract: MIL-101(Cr), an achiral metal–organic framework, made up of a terephthalic acid ligand and a metal chromium ion was selected as a template. Its structural features are unsaturated Lewis acid sites that can be easily activated… read more here.
Keywords: organic frameworks; development chiral; metal organic; mil 101 ... See more keywords