Fabrication of trifunctional polyoxometalate - decorating chitosan nanofibers in highly selective production of DFF from 5-HMF, fructose and glucose.
Sign Up to like & getrecommendations! Published in 2019 at "ChemSusChem"
DOI: 10.1002/cssc.201901384
Abstract: Trifunctional polyoxometalate (POM) decorating chitosan nanofibers (H5PMo10V2O40/chitosan nanofibers, abbreviated as HPMoV/CS-f) had been synthesized using electrospinning method, which realized highly efficient oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF). Decorating chitosan nanofibers by POMs generated enhanced… read more here.
Keywords: fructose glucose; trifunctional polyoxometalate; dff; chitosan nanofibers ... See more keywords
Selective Electrosynthesis of 2,5-diformylfuran (DFF) in a Continuous Flow System.
Sign Up to like & getrecommendations! Published in 2021 at "ChemSusChem"
DOI: 10.1002/cssc.202102596
Abstract: The gram-scale selective oxidation of biomass-based chemicals, in particular 5-hydroxymethylfurfural (HMF), into value-added 2,5-diformylfuran (DFF) has a high application potential but suffers from high cost, low selectivity and needs harsh reaction conditions. Besides, electrooxidation strategy… read more here.
Keywords: dff; system; flow system; continuous flow ... See more keywords
Mechanistic kinetic modelling of enzyme-catalysed oxidation reactions of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA)
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Science"
DOI: 10.1016/j.ces.2021.116982
Abstract: Abstract Six enzymes were tested against HMF and its oxidation intermediates to determine substrate specificity, product yield and pathways. A Michaelis–Menten kinetic mathematical model was constructed and some rate parameters calculated. The best 2,5-diformylfuran (DFF)… read more here.
Keywords: enzyme reactions; oxidation; dff; mechanistic kinetic ... See more keywords
Efficient Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran over Fe2O3-Promoted MnO2 Catalyst
Sign Up to like & getrecommendations! Published in 2019 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.9b00010
Abstract: It is challenging to effectively convert 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF), a flexible biobased building-block, over non-noble metal catalysts. In this contribution, Mn–Fe oxides were prepared and served as highly active catalysts for the selective… read more here.
Keywords: efficient aerobic; oxidation; catalyst; dff ... See more keywords
Enzymatic conversion reactions of 5-hydroxymethylfurfural (HMF) to bio-based 2,5-diformylfuran (DFF) and 2,5-furandicarboxylic acid (FDCA) with air: mechanisms, pathways and synthesis selectivity
Sign Up to like & getrecommendations! Published in 2020 at "Biotechnology for Biofuels"
DOI: 10.1186/s13068-020-01705-z
Abstract: 2,5-Furandicarboxylic acid (FDCA) is one of the top biomass-derived value-added chemicals. It can be produced from fructose and other C6 sugars via formation of 5-hydroxymethilfurfural (HMF) intermediate. Most of the chemical methods for FDCA production… read more here.
Keywords: acid fdca; furandicarboxylic acid; conversion; dff ... See more keywords
Effect of Dentin Desensitizer Containing Novel Bioactive Glass on the Permeability of Dentin
Sign Up to like & getrecommendations! Published in 2022 at "Materials"
DOI: 10.3390/ma15124041
Abstract: The objective of this study was to evaluate the effect of novel bioactive glass (BAG)-containing desensitizers on the permeability of dentin. Experimental dentin desensitizers containing 3 wt% BAG with or without acidic functional monomers (10-MDP… read more here.
Keywords: spectroscopy; bag; dentin; permeability dentin ... See more keywords
Photocatalytic Aerobic Oxidation of Biomass-Derived 5-HMF to DFF over MIL-53(Fe)/g-C3N4 Composite
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27238537
Abstract: A MIL-53(Fe)/g-C3N4 heterogeneous composite was synthesized and applied in photocatalytic oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF). The systematic investigation indicated that the introduction of MIL-53(Fe) into g-C3N4 increased the specific surface area, broadened the… read more here.
Keywords: oxidation; c3n4 composite; mil c3n4; mil ... See more keywords