Articles with "dgpy" as a keyword



Panchromatic Absorption and Oxidation of an Iron(II) Spin Crossover Complex.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c03511

Abstract: In order to expand and exploit the useful properties of d6-iron(II) and d5-iron(III) complexes in potential magnetic, photophysical, or magnetooptical applications, crucial ligand-controlled parameters are the ligand field strength in a given coordination mode and… read more here.

Keywords: panchromatic absorption; iron; dgpy; ligand ... See more keywords

The Full d3-d5 Redox Series of Mononuclear Manganese Complexes: Geometries and Electronic Structures of [Mn(dgpy)2]n.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c01680

Abstract: Although manganese ions exhibit a rich redox chemistry, redox processes are often accompanied by structural reorganization and a high propensity for ligand substitution, so that no complete structurally characterized manganese(II,III,IV) complex series without significant ligand… read more here.

Keywords: series; manganese iii; chemistry; dgpy ... See more keywords

Thermally Activated and Nonactivated Excited State Decay of [Cr(dgpy)2]3+

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Published in 2025 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.5c03668

Abstract: Photoactive and luminescent chromium(III) complexes are typically coordinated by aromatic N-heterocyclic chelate ligands such as polypyridines. Photoluminescence quantum yields and lifetimes can achieve up to 30% and several milliseconds, respectively. The effect of aliphatic N-donor… read more here.

Keywords: spectroscopy; chemistry; thermally activated; activated nonactivated ... See more keywords