Investigation on a Novel Mixed Dialkyl Oxalate System as an Oxygenated Fuel Additive
Sign Up to like & getrecommendations! Published in 2020 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.9b04536
Abstract: The Mixed dialkyl oxalates (mDAO) system can be industrially synthesized inexpensively from CO with methanol, ethanol and mixed alcohols, which are widely available from CO-rich industrial waste ga... read more here.
Keywords: system; investigation novel; novel mixed; mixed dialkyl ... See more keywords
Cis-1,4-Polymerization of Isoprene Catalyzed by 1,3-Bis(2-pyridylimino)isoindoline-Ligated Rare-Earth-Metal Dialkyl Complexes
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DOI: 10.1021/acs.organomet.7b00322
Abstract: The two rare-earth-metal dialkyl complexes 1 and 2 (1, Ln = Sc; 2, Ln = Lu) were obtained via the same acid–base reaction between 1,3-bis(2-pyridylimino)isoindoline (BPI) ligand and rare-earth-metal trialkyl complexes. These complexes 1 and… read more here.
Keywords: isoindoline; dialkyl; rare earth; earth metal ... See more keywords
Ni-Catalyzed Enantioselective Dialkyl Carbinol Synthesis via Decarboxylative Cross-Coupling: Development, Scope, and Applications.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c04358
Abstract: The first enantioselective decarboxylative Negishi-type alkylations of α-oxy carboxylic acids are reported via the intermediacy of redox-active esters (RAEs). This transformation enables a radical-based retrosynthesis of seemingly trivial enantiopure dialkyl carbinols. This article includes a… read more here.
Keywords: dialkyl; synthesis; coupling development; enantioselective dialkyl ... See more keywords