Intramolecular Cyclizations of Vinyl-Substituted N,N-Dialkyl Arylamines Enabled by Borane-Assisted Hydride Transfer
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DOI: 10.1021/acscatal.8b04485
Abstract: Catalytic amounts of B(C6F5)3 have been found to be able to promote the intramolecular cyclization of vinyl-substituted N,N-dialkyl arylamines to afford nitrogen-containing heterocycles. Our mechanistic studies indicate the reaction is initiated by abstraction of an… read more here.
Keywords: hydride; substituted dialkyl; dialkyl arylamines; intramolecular cyclizations ... See more keywords