Synthesis of Fluorinated Dialkyl Carbonates from Carbon Dioxide as a Carbonyl Source.
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DOI: 10.1002/cssc.202000090
Abstract: Fluorinated dialkyl carbonates, which serve as environmentally benign phosgene substitutes, were successfully produced from carbon dioxide either directly or indirectly. Nucleophilic addition of 2,2,2-trifluoroethanol to carbon dioxide and subsequent reaction with 2,2,2-trifluoroethyltriflate ( E OTf… read more here.
Keywords: dioxide carbonyl; fluorinated dialkyl; dialkyl carbonates; carbon dioxide ... See more keywords
Ash Catalyzed Synthesis of Long-Chain Dialkyl Carbonates Through Carbonyl Exchange Reaction
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DOI: 10.1007/s10562-019-03004-1
Abstract: Abstract Present work is focused on development of methodology involving utilization of cost effective, highly effective heterogeneous catalyst prepared from wood ash for carbonyl exchange reaction between long chain alcohols and diethyl carbonate to produce… read more here.
Keywords: chain; dialkyl carbonates; long chain; carbonyl exchange ... See more keywords
Energy issues in the utilization of CO2 in the synthesis of chemicals:The case of the direct carboxylation of alcohols to dialkyl-carbonates
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DOI: 10.1016/j.cattod.2016.02.046
Abstract: This paper aims at highlighting the hurdles and traps on the way back from CO2 to chemicals (or even fuels). The case of the synthesis of dialkyl carbonates is discussed, considering several synthetic conditions and… read more here.
Keywords: energy; energy issues; case; dialkyl carbonates ... See more keywords
Sustainable Valorisation of Renewables through Dialkyl Carbonates and Isopropenyl Esters
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DOI: 10.1039/d2gc04145f
Abstract: This review showcases a thorough analysis of reactions and applications of the most widespread linear and alkylene organic carbonates (DACs) as dimethyl-, diethyl-, ethylene-, and propylene- carbonates (DMC, DEC, EC,... read more here.
Keywords: renewables dialkyl; valorisation renewables; carbonates isopropenyl; isopropenyl esters ... See more keywords