From hypochlorites to perfluorinated dialkyl peroxides
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DOI: 10.1016/j.jfluchem.2019.109416
Abstract: Abstract The synthesis and characterization of the new perfluorinated hypochlorite, undecafluoro-tert-pentyl hypochlorite, (C2F5)(F3C)2COCl, is reported. Its gas-phase infrared, UV/Vis and NMR spectra have been recorded and its spectroscopic properties are discussed and compared with quantum-chemical… read more here.
Keywords: perfluorinated dialkyl; chemistry; dialkyl peroxides; hypochlorites perfluorinated ... See more keywords
Ultrasound-Assisted Green Synthesis of Dialkyl Peroxides under Phase-Transfer Catalysis Conditions
Sign Up to like & getrecommendations! Published in 2019 at "Molecules"
DOI: 10.3390/molecules25010118
Abstract: The dialkyl peroxides, which contain a thermally unstable oxygen–oxygen bond, are an important source of radical initiators and cross-linking agents. New efficient and green methods for their synthesis are still being sought. Herein, ultrasound-assisted synthesis… read more here.
Keywords: ultrasound assisted; phase transfer; synthesis dialkyl; dialkyl peroxides ... See more keywords