Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines.
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DOI: 10.1039/d1cc00318f
Abstract: Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(iii) macrocycle [{LAl(pyridyl)}6], which represents the first dialumane-mediated C-H activation of Py and may suggest a new… read more here.
Keywords: dialumane; organometallo macrocycle; mediated activation; activation ... See more keywords