Reductive activation of N2 using a calcium/potassium bimetallic system supported by an extremely bulky diamide ligand.
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DOI: 10.1039/d2cc04841h
Abstract: An extremely bulky xanthene bridged diamide ligand (TCHPNON = 4,5-bis(2,4,6-tricyclohexylanilido)-2,7-diethyl-9,9-dimethyl-xanthene) has been developed and used to prepare two monomeric diamido-calcium complexes [(TCHPNON)Ca(D)n] (D = THF, n = 2, 3; D = toluene, n = 1,… read more here.
Keywords: calcium; extremely bulky; activation using; reductive activation ... See more keywords