Facile Transformations of a Binuclear Cp*Co(II) Diamidonaphthalene Complex to Mixed-Valent Co(II)Co(III), Co(III)(μ-H)Co(III), and Co(III)(μ-OH)Co(III) Derivatives.
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DOI: 10.1021/acs.inorgchem.1c03451
Abstract: A diamido-bridged dicobalt complex supported by a diamidonaphthalene ligand, Cp*2Co2(μ-1,8-C10H8(NH)2) (1), was synthesized, and the reactivity relevant to redox transformations of the Co2N2 core was investigated. It was found that the Co(II)-Co(II) bond allows for… read more here.
Keywords: mixed valent; iii; iii iii; diamidonaphthalene ... See more keywords