In situ simultaneous electrochemical ESR study of radicals generated from 2,2-dinitroethene-1,1-diamine (FOX-7). Intramolecular chemical exchange resulting in an alternation line-width effect.
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DOI: 10.1016/j.jmr.2020.106895
Abstract: The molecule of 2,2-dinitroethene-1,1-diamine (FOX-7) is one of the most interesting molecules with multiple redox centres stabilized by push-pull effect. To reveal the detailed mechanism of its electrochemical process radical intermediates formed in the course… read more here.
Keywords: dinitroethene diamine; diamine fox; effect; situ simultaneous ... See more keywords