Photoexcited Copper-Catalyzed Difunctionalization of Alkenes for the Synthesis of 2,5-Diamino Acid Derivatives via Uncommon 1,2-Hydrogen Atom Transfer of Amidyl Radicals.
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DOI: 10.1021/acs.orglett.5c01633
Abstract: Compared with 1,5-hydrogen atom transfer (1,5-HAT) processes, 1,2-HAT processes have been reported less frequently. And, the synthesis of 2,5-diamino acid derivatives via a mild photocatalytic approach has not been reported yet. Herein, we report a… read more here.
Keywords: diamino acid; synthesis diamino; hydrogen atom; derivatives via ... See more keywords