One‐Pot Solvent‐Free Synthesis of Diaryl 1,2‐Diketones by the Sequential Heck Oxidation Reaction of Aryl Halides with Styrenes
Sign Up to like & getrecommendations! Published in 2017 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.201600529
Abstract: A novel one-pot procedure for the synthesis of benzil derivatives was developed by the sequential Heck oxidation reaction of aryl halides (I and Br) with styrenes. In situ-generated stilbene scaffolds were directly converted to the… read more here.
Keywords: oxidation; diaryl diketones; reaction; one pot ... See more keywords
TBAI-Catalyzed Oxidative Coupling of Benzyl Ketones to Synthesize 2,3-Diaryl-1,4-Diketones in Water
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c06216.s001
Abstract: An efficient and green route of C–C bond formation was disclosed to construct 2,3-diaryl-1,4-diketones from α-methylene ketones by the catalysis of tetrabutylammonium iodide (TBAI) with tert-butyl hydroperoxide (TBHP) as an oxidant in water. This reaction… read more here.
Keywords: catalyzed oxidative; diaryl diketones; water; coupling benzyl ... See more keywords