Catalytic Asymmetric Diarylation of Internal Acyclic Styrenes and Enamides.
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DOI: 10.1021/jacs.2c03411
Abstract: Enantioselective transformations of olefins are among the most important strategies for the asymmetric synthesis of organic compounds. Chemo-, diastereo-, and stereoselective control of reactions with internal acyclic alkenes for the construction of functionalized acyclic alkanes… read more here.
Keywords: diarylation; asymmetric diarylation; internal acyclic; diarylation internal ... See more keywords
Nickel-Catalyzed Stereoselective Diarylation of Alkenylarenes.
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DOI: 10.1021/jacs.8b05680
Abstract: A three-component coupling of aryl bromides, arylboron reagents, and alkenylarenes is presented. The method tolerates a variety of substitution patterns on all of the components. In particular, 1,2-disubstituted alkenylarenes are suitable and undergo highly diastereoselective… read more here.
Keywords: stereoselective diarylation; catalyzed stereoselective; diarylation; diarylation alkenylarenes ... See more keywords