Palladium-Catalyzed Cross-Electrophile Coupling between Aryl Diazonium Salt and Aryl Iodide/Diaryliodonium Salt in H2O-EtOH.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03932
Abstract: We report herein a mild highly chemoselective palladium-catalyzed cross-electrophile coupling between readily accessible aromatic diazonium salt and aryl iodide or diaryliodonium salt in water-ethanol (2:1) medium. Mechanistic studies revealed that ethanol is crucial to generate… read more here.
Keywords: aryl iodide; iodide diaryliodonium; diaryliodonium salt; diazonium salt ... See more keywords
Cu(ii)-catalyzed sulfide construction: both aryl groups utilization of intermolecular and intramolecular diaryliodonium salt.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c6cc09201b
Abstract: A sulfur-iodine exchange protocol of diaryliodonium salts with inorganic sulfur salt was developed. Both aryl groups in the diaryliodonium salt were fully exerted in this transformation. Five- to eight-membered sulfur-containing heterocycles were achieved. Note that… read more here.
Keywords: aryl groups; sulfide construction; catalyzed sulfide; salt ... See more keywords
Silicon nanosheets as co-initiators for diaryliodonium induced radical and cationic polymerization.
Sign Up to like & getrecommendations! Published in 2019 at "Nanotechnology"
DOI: 10.1088/1361-6528/aaf3f2
Abstract: A system of silicon nanosheets and a diaryliodonium salt was found to initiate cationic and radical polymerizations. The polymerization relies on a syngergistic interaction between the silicon nanomaterial and the diaryliodonium salt, whereby the silicon… read more here.
Keywords: nanosheets initiators; polymerization; silicon nanosheets; diaryliodonium salt ... See more keywords