Catalytic Enantioselective Synthesis of Axially Chiral Diarylmethylidene Indanones.
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DOI: 10.1021/acs.orglett.1c01671
Abstract: We describe the first atropselective Suzuki-Miyaura cross-coupling of β-keto enol triflates to access axially chiral (Z)-diarylmethylidene indanones (DAIs). The chemical, physical, and biological properties of DAIs are unknown, despite their being structurally similar to arylidene… read more here.
Keywords: catalytic enantioselective; diarylmethylidene indanones; chiral diarylmethylidene; axially chiral ... See more keywords