Diastereofacial π-Stacking as an Approach To Access an Axially Chiral P,N-Ligand for Asymmetric Catalysis
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DOI: 10.1021/acscatal.6b03427
Abstract: A phosphino-imidazoline (PHIM) ligand possessing axial chirality is prepared in a straightforward five-step synthesis. Configurational stability around the chiral axis is achieved by the diastereofacial π-stacking between the pentafluorophenyl and the naphthalene rings. In particular,… read more here.
Keywords: catalysis diastereofacial; approach access; ligand; stacking approach ... See more keywords