Synthesis and structure of manganese(ii) coordination polymers with 1,4-diazabicyclo[2.2.2]octane N, N′-dioxide: solvent and template effects
Sign Up to like & getrecommendations! Published in 2020 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-020-2930-4
Abstract: New metal-organic frameworks [Mn(DMF)2(odabco)2](ClO4)2 · H2O (1), [Mn(H2O)2− (HCOO)2] · odabco (2), and [Mn(Hodabco)2(odabco)3](NO3)4 (3) were synthesized by the reaction of manganese Perchlorate with 1,4-diazabicyclo[2.2.2]octane N,N′-dioxide (odabco) in N, N-dimethylformamide (DMF) under varying reaction conditions.… read more here.
Keywords: diazabicyclo octane; coordination; thf; dmf ... See more keywords
Molecular structure, interatomic interactions and vibrational analysis of 1,4-diazabicyclo[3.2.1]octane parent ring system
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DOI: 10.1016/j.molstruc.2016.10.065
Abstract: Abstract Molecular structure of 1,4-diazabicyclo[3.2.1]octane, a parent ring of TAN1251 family of alkaloids, is herein characterized for the first time in comparison with the structure of nortropane (8-azabicyclo[3.2.1]octane), the parent framework of tropane ring system.… read more here.
Keywords: diazabicyclo octane; molecular structure; analysis; octane parent ... See more keywords
Electrochemical and microbiological insights into the use of 1,4-diazabicyclo[2.2.2]octane-functionalized anion exchange membrane in microbial fuel cell: A benchmarking study with Nafion
Sign Up to like & getrecommendations! Published in 2020 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2019.116478
Abstract: Abstract In this work, two polymeric membrane separators (a proton exchange membrane (PEM), Nafion, and an anion-exchange membrane (AEM), 1,4-diazabicyclo[2.2.2]octane (DABCO)-functionalized PSEBS) deployed in microbial fuel cells (MFCs) are comparatively assessed. The performances of MFCs… read more here.
Keywords: diazabicyclo octane; anion exchange; exchange membrane; acetate ... See more keywords
Self-Assembling Metallocomplexes of the Amphiphilic 1,4-Diazabicyclo[2.2.2]octane Derivative as a Platform for the Development of Nonplatinum Anticancer Drugs
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c06465
Abstract: New 1-cetyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide complexes with copper(II) bromide and lanthanum(III) nitrate were characterized using dynamic light scattering and transmission electron microscopy, with self-assembly and the morphological behavior elucidated. For the lanthanum(III) nitrate complex, the 3D crystal… read more here.
Keywords: assembling metallocomplexes; diazabicyclo octane; metallocomplexes amphiphilic; octane derivative ... See more keywords
Thermally Activated Transient Dipoles and Rotational Dynamics of Hydrogen-Bonded and Charge-Transferred Diazabicyclo [2.2.2]octane Molecular Rotors.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b07518
Abstract: We present here dielectric properties and rotational dynamics of cocrystals formed with either triphenylacetic acid (cocrystal I) or 9,10-triptycene dicarboxylic acid (cocrystal II), as hydrogen bonding donors, and diazabicyclo[2.2.2]octane (DABCO) as a ditopic hydrogen bond… read more here.
Keywords: hydrogen bonded; diazabicyclo octane; thermally activated; hydrogen ... See more keywords
Synthesis of Dihydropyrimidinones (DHPMs) and Hexahydro Xanthene Catalyzed by 1,4-Diazabicyclo [2.2.2] Octane Triflate Under Solvent-Free Condition.
Sign Up to like & getrecommendations! Published in 2019 at "Current organic synthesis"
DOI: 10.2174/1570179415666181113154232
Abstract: OBJECTIVE DABCO salts were evaluated as catalysts for the Biginelli reaction between 4- methoxybenzaldehyde, urea and ethyl acetoacetate under solvent-free conditions. 1,4-Diazabicyclo [2.2.2] octane triflate was found to be a simple, inexpensive, highly efficient catalyst… read more here.
Keywords: diazabicyclo octane; ethyl acetoacetate; octane triflate; reaction ... See more keywords