1,3,2‐Diazaphospholenes Catalyze the Conjugate Reduction of Substituted Acrylic Acids
Sign Up to like & getrecommendations! Published in 2020 at "ChemCatChem"
DOI: 10.1002/cctc.202000662
Abstract: The potent nucleophilicity and remarkably low basicity of 1,3,2‐diazaphospholenes (DAPs) is exploited in a catalytic, metal‐free 1,4‐reduction of free α,β‐unsaturated carboxylic acids. Notably, the reduction occurs without a prior deprotonation of the carboxylic acid moiety… read more here.
Keywords: reduction; reduction substituted; catalyze conjugate; diazaphospholenes catalyze ... See more keywords