Copper-Catalyzed Ligand-Free Diazidation of Olefins with TMSN3 in CH3CN or in H2O.
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DOI: 10.1021/acs.orglett.7b02982
Abstract: An environmentally benign, copper-catalyzed diazidation of a broad range of olefins, including vinylarenes, unactivated alkenes, allene, and dienes, under mild conditions with TMSN3 (trimethylazidosilane) as azido source, has been developed. This reaction can be carried… read more here.
Keywords: free diazidation; ligand free; copper catalyzed; diazidation ... See more keywords