An Unconventional Reaction of 2,2-Diazido Acylacetates with Amines
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DOI: 10.1002/ejoc.201601625
Abstract: We have discovered that 2,2-diazido acylacetates, a class of compounds with essentially unknown reactivity, can be coupled to amines through a new strategy that does not involve any reagents. 2,2-Diazido acetate is the unconventional leaving… read more here.
Keywords: reaction diazido; unconventional reaction; acylacetates amines; diazido acylacetates ... See more keywords
SYNTHESIS, STRUCTURE, AND CHARACTERIZATION OF HIGH-ENERGY 4,6-DIAZIDO- N -(4,6-DIAZIDO-1,3,5-TRIAZIN-2-YL)-1,3,5-TRIAZIN-2-AMINE
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DOI: 10.1007/3718
Abstract: The high-energy compound 4,6-diazido- N -(4,6-diazido-1,3,5-triazin-2-yl)-1,3,5-triazin-2-amine was obtained in high yield by azidation of 4,6-dichloro- N -(4,6-dichloro-1,3,5-triazin-2-yl)-1,3,5-triazin-2-amine with sodium azide in acetone. According to 13 ะก and 15 N NMR spectral data, the obtained tetraazide… read more here.
Keywords: high energy; diazido; triazin; triazin triazin ... See more keywords