Iron and Cobalt Diazoalkane Complexes Supported by β-Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation.
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DOI: 10.1021/acs.inorgchem.8b00468
Abstract: Diazoalkanes are interesting redox-active ligands and also precursors to carbene fragments. We describe a systematic study of the binding and electronic structure of diphenyldiazomethane complexes of β-diketiminate supported iron and cobalt, which span a range… read more here.
Keywords: cobalt; diazoalkane; diazoalkane complexes; iron cobalt ... See more keywords