Amine‐Substituted Diazocine Derivatives – Synthesis, Structure, and Photophysical Properties
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DOI: 10.1002/hlca.201800146
Abstract: 1 Amine-substituted Diazocine Derivatives – Synthesis, Structure and Photophysical Properties Mark A. Gregory, Bolong Zhang, b Andrew J. Tilley, b Tamika Scheerlinck, Jonathan M. White, and Wallace W. H. Wong* b a School of Chemistry,… read more here.
Keywords: amine substituted; diazocine derivatives; chemistry; derivatives synthesis ... See more keywords
Synthesis of Chiral Diazocine Derivatives via a Copper-Catalyzed Dearomative [5+3] Cycloaddition.
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DOI: 10.1021/acs.orglett.2c01389
Abstract: Copper-catalyzed [5+3] cycloaddition of N-aromatic zwitterions and enol diazoacetates produced enantio-enriched diazocine derivatives. A sterically encumbered BOX ligand and NaBArF additive played significant roles in driving the overall catalytic process via the unfavorable dearomatization to… read more here.
Keywords: cycloaddition; copper catalyzed; synthesis chiral; diazocine derivatives ... See more keywords