Boron-Catalyzed O-H Bond Insertion of α-Aryl α-Diazoesters in Water.
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DOI: 10.1021/acs.orglett.8b01988
Abstract: A catalytic, metal-free O-H bond insertion of α-diazoesters in water in the presence of B(C6F5)3· nH2O (2 mol %) was developed, affording a series of α-hydroxyesters in good to excellent yields. The reaction features easy… read more here.
Keywords: water; bond insertion; boron catalyzed; diazoesters water ... See more keywords