Articles with "diazoimine" as a keyword



Metal-Free Synthesis of (E)-Monofluoroenamine from 1-Sulfonyl-1,2,3-triazole and Et2O·BF3 via Stereospecific Fluorination of α-Diazoimine.

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Published in 2018 at "Organic letters"

DOI: 10.1021/acs.orglett.7b04014

Abstract: A general, stereospecific, and straightforward method for the rapid preparation of functionalized (E)-monofluoroenamines is reported. Rather than transition metals (Rh, Ni, Pd, Cu, Ag, etc.), Et2O·BF3 was employed to promote the formation of α-diazoimine through… read more here.

Keywords: diazoimine; sulfonyl triazole; et2o bf3;