Photocatalytic Arylations with Diazonium Salts in Aqueous and Biorelevant Media
Sign Up to like & getrecommendations! Published in 2025 at "ChemCatChem"
DOI: 10.1002/cctc.202401778
Abstract: Performing designed, abiotic chemical transformations in live environments represents a powerful approach to interrogate and manipulate biology, and to uncover new types of biomedical tools. Despite significant advances in the area, the list of bio‐orthogonal… read more here.
Keywords: photocatalytic arylations; aqueous biorelevant; media photocatalytic; salts aqueous ... See more keywords
Alternative method for the synthesis of triazenes from aryl diazonium salts
Sign Up to like & getrecommendations! Published in 2021 at "Tetrahedron"
DOI: 10.1016/j.tet.2021.132185
Abstract: Abstract An alternative mild method for access to 1-aryl-3,3-dimethyl alkyl triazenes is described. This protocol employs the dropwise addition of a methanolic solution of a carboxylate (RCO2M) or carbonate (CO32-) to a gently heated DMF… read more here.
Keywords: method synthesis; aryl diazonium; diazonium; alternative method ... See more keywords
Renaissance of Sandmeyer-Type Reactions: Conversion of Aromatic C-N Bonds into C-X Bonds (X = B, Sn, P, or CF3).
Sign Up to like & getrecommendations! Published in 2018 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.7b00566
Abstract: The Sandmeyer reaction represents an important organic transformation that converts an arylamine to an aryl halide using Cu(I) halide via a diazonium salt intermediate. The reaction was first reported by Sandmeyer in 1884, and a… read more here.
Keywords: chemistry; sandmeyer type; reaction; diazonium ... See more keywords
Diazo Activation with Diazonium Salts: Synthesis of Indazole and 1,2,4-Triazole.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01232
Abstract: A donor/acceptor diazo activation strategy, processing via condensation using diazonium salts without the addition of any other catalysts or reagents, is reported. The diazenium intermediate was found to undergo cyclization to give indazoles in excellent… read more here.
Keywords: diazonium salts; salts synthesis; activation diazonium; diazo activation ... See more keywords
One-Step Transformation of Aryl Diazonium Salts into Aryl Indium(III) Reagents.
Sign Up to like & getrecommendations! Published in 2024 at "Organic letters"
DOI: 10.1021/acs.orglett.4c01448
Abstract: A method for the conversion of diazonium salts into intrinsically nucleophilic aryl indium reagents is described. The reaction is performed using indium(I) bromide with the C-In bond being formed by the interaction of aryl radicals… read more here.
Keywords: indium iii; aryl indium; indium; iii reagents ... See more keywords
Plasmon-Induced Nanolocalized Reduction of Diazonium Salts
Sign Up to like & getrecommendations! Published in 2017 at "ACS Omega"
DOI: 10.1021/acsomega.7b00394
Abstract: Surface grafting from diazonium solutions triggered by localized surface plasmon has been investigated. An organic layer that is 20–30 nm thick is easily grafted onto gold nanoparticles (AuNPs) by visible-light illumination in a few minutes… read more here.
Keywords: diazonium salts; nanolocalized reduction; reduction diazonium; diazonium ... See more keywords
Radiometal-Containing Aryl Diazonium Salts for Chemoselective Bioconjugation of Tyrosine Residues
Sign Up to like & getrecommendations! Published in 2019 at "ACS Omega"
DOI: 10.1021/acsomega.9b03248
Abstract: Tyrosine is an attractive target for chemo- and site-selective protein modification. The particular chemical nature of tyrosine residues allows bioconjugation chemistry with reactive aryl diazonium salts via electrophilic aromatic substitution to produce diazo compounds. In… read more here.
Keywords: chemistry; tyrosine; tyrosine residues; 64cu 68ga ... See more keywords
Transition-metal-free, visible-light-mediated cyclization of o-azidoarylalkynes with aryl diazonium salts
Sign Up to like & getrecommendations! Published in 2017 at "New Journal of Chemistry"
DOI: 10.1039/c7nj03144k
Abstract: Visible light along with 3 mol% eosin Y catalyzes the cyclization reaction of o-azidoarylalkynes with aryl diazonium salts by a photoredox process. We have investigated the scope of the reaction for several aryl diazonium salts… read more here.
Keywords: azidoarylalkynes aryl; transition metal; visible light; diazonium salts ... See more keywords
Novel synthesis of 1,2-diaza-1,3-dienes with potential biological activity from cinnamic acids and diazonium salts of anilines
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra07515f
Abstract: Cinnamic acids are an important class of phenolic compounds, which have many beneficial effects on human health but are also interesting synthetic intermediates thanks to the presence of several reactive sites. While studying the reactivity… read more here.
Keywords: diaza dienes; diazonium salts; cinnamic acids; biological activity ... See more keywords
A chemoselective hydroxycarbonylation and 13C-labeling of aryl diazonium salts using formic acid as the C-1 source.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc04758c
Abstract: We report a one-pot synthesis of aryl carboxylic acids utilizing HCOOH as a CO surrogate with low Pd-catalyst loading. This operationally simple and scalable method does not require use of a high-pressure reactor, two-chamber reaction… read more here.
Keywords: labeling aryl; chemoselective hydroxycarbonylation; hydroxycarbonylation 13c; 13c labeling ... See more keywords
Grafting of Diazonium Salts on Surfaces: Application to Biosensors
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DOI: 10.3390/bios10010004
Abstract: This review is divided into two parts; the first one summarizes the main features of surface modification by diazonium salts with a focus on most recent advances, while the second part deals with diazonium-based biosensors… read more here.
Keywords: grafting diazonium; surfaces application; diazonium; diazonium salts ... See more keywords