Transition Metal-Catalyzed Dicarbofunctionalization of Unactivated Olefins.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical record"
DOI: 10.1002/tcr.201700098
Abstract: Transition metal (TM)-catalyzed difunctionalization of unactivated olefins with two carbon-based entities is a powerful method to construct complex molecular architectures rapidly from simple and readily available feedstock chemicals. While dicarbofunctionalization of unactivated olefins has a… read more here.
Keywords: transition metal; unactivated olefins; dicarbofunctionalization unactivated; metal catalyzed ... See more keywords
Nickel-Catalyzed Reductive Dicarbofunctionalization of Vinylarenes Enabled by Electrochemical Process.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02976
Abstract: An intermolecular alkene dicarbofunctionalization via electrochemical reduction that combines alkyl and aryl iodides with styrene derivatives was herein reported. The multicomponent reaction exhibited several synthetic advantages including simple operation, wide substrate scope, and convenience of… read more here.
Keywords: reductive dicarbofunctionalization; nickel catalyzed; dicarbofunctionalization; vinylarenes enabled ... See more keywords
Three-Component Olefin Dicarbofunctionalization Enabled by Nickel/Photoredox Dual Catalysis.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b08282
Abstract: An intermolecular, photocatalytic dicarbofunctionalization (DCF) of olefins enabled by the merger of Giese-type addition with Ni/photoredox dual catalysis has been realized. Capitalizing on the rapid addition of 3° radicals to alkenes and their reluctance toward… read more here.
Keywords: olefin; photoredox dual; three component; dicarbofunctionalization ... See more keywords