Transition Metal-Catalyzed Dicarbofunctionalization of Unactivated Olefins.
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DOI: 10.1002/tcr.201700098
Abstract: Transition metal (TM)-catalyzed difunctionalization of unactivated olefins with two carbon-based entities is a powerful method to construct complex molecular architectures rapidly from simple and readily available feedstock chemicals. While dicarbofunctionalization of unactivated olefins has a… read more here.
Keywords: transition metal; unactivated olefins; dicarbofunctionalization unactivated; metal catalyzed ... See more keywords
Nickel-Catalyzed Reductive Dicarbofunctionalization of Vinylarenes Enabled by Electrochemical Process.
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DOI: 10.1021/acs.orglett.2c02976
Abstract: An intermolecular alkene dicarbofunctionalization via electrochemical reduction that combines alkyl and aryl iodides with styrene derivatives was herein reported. The multicomponent reaction exhibited several synthetic advantages including simple operation, wide substrate scope, and convenience of… read more here.
Keywords: reductive dicarbofunctionalization; nickel catalyzed; dicarbofunctionalization; vinylarenes enabled ... See more keywords
Photoinduced Pd-Catalyzed 1,4-Dicarbofunctionalization of 1,3-Butadienes via Aliphatic C-H Bond Elaboration.
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DOI: 10.1021/acs.orglett.4c04410
Abstract: A three-component coupling strategy for 1,4-dicarbofunctionalization of 1,3-butadiene with C-H bearing substrates has been developed using photoinduced Pd catalysis, with aryl bromide serving as the hydrogen atom transfer (HAT) reagent. This photocatalytic coupling process achieves… read more here.
Keywords: photoinduced catalyzed; via aliphatic; dicarbofunctionalization; catalyzed dicarbofunctionalization ... See more keywords
Three-Component Olefin Dicarbofunctionalization Enabled by Nickel/Photoredox Dual Catalysis.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b08282
Abstract: An intermolecular, photocatalytic dicarbofunctionalization (DCF) of olefins enabled by the merger of Giese-type addition with Ni/photoredox dual catalysis has been realized. Capitalizing on the rapid addition of 3° radicals to alkenes and their reluctance toward… read more here.
Keywords: olefin; photoredox dual; three component; dicarbofunctionalization ... See more keywords
Regioselective Transformations of Unsaturated Systems Catalyzed by Low-Valent Nickel: Cycloaddition, Hydrosilylation, and Dicarbofunctionalization
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DOI: 10.1055/a-2591-9299
Abstract: In this Account, we describe our recent research progress in the development of the functionalization of unsaturated substrates catalyzed by low-valent nickel. In particular, we discuss nickel-catalyzed azide–alkyne cycloaddition (NiAAC), [2 + 2 + 2]… read more here.
Keywords: dicarbofunctionalization; catalyzed low; nickel; hydrosilylation ... See more keywords
Photoinduced Pd-Catalyzed Selective 1,4-Dicarbofunctionalization of 1,3-Butadiene with Alkyl or Aryl Bromides and Oxindoles
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DOI: 10.1055/a-2700-2940
Abstract: The dicarbofunctionalization of 1,3-butadiene provides rapid access to complex allyl compounds in organic synthesis. Here we report a photoinduced palladium-catalyzed three-component coupling that enables selective 1,4-dicarbofunctionalization of 1,3-butadiene with alkyl or aryl bromides and oxindole… read more here.
Keywords: dicarbofunctionalization; alkyl aryl; dicarbofunctionalization butadiene; butadiene alkyl ... See more keywords