Stability of nickel bis(dicarbollide) complexes
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DOI: 10.1016/j.mencom.2019.09.019
Abstract: Reactions of nickel( iv ) bis(dicarbollide) with 2,2′-bipyridine or 1,10-phenanthroline in ethanol result in destruction of the metallacarborane cage with formation of the parent and 3-ethoxy substituted nido-carboranes. read more here.
Keywords: stability nickel; nickel bis; bis dicarbollide; dicarbollide complexes ... See more keywords
Bis(Dicarbollide) Complexes of Transition Metals: How Substituents in Dicarbollide Ligands Affect the Geometry and Properties of the Complexes
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DOI: 10.3390/molecules29153510
Abstract: The interaction between different types of substituents in dicarbollide ligands and their influence on the stabilization of various rotational conformers (rotamers) of transition metal bis(dicarbollide) complexes [3,3′-M(1,2-C2B9H11)2]− are considered. It has been shown that the… read more here.
Keywords: bis dicarbollide; transition; dicarbollide; geometry ... See more keywords