Rh-Catalyzed Coupling of Cyclic 1,3-Dicarbonyl-Derived Iodonium Ylides with Cyclopropanols.
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DOI: 10.1021/acs.orglett.5c00598
Abstract: Herein, we report a modular α-monoalkylation of cyclic 1,3-dicarbonyls with cyclopropyl alcohols through a cyclic iodonium ylide strategy. This approach is general, base-free, operationally simple, and suitable for various medically important (hetero)cyclic 1,3-dicarbonyls. A wide… read more here.
Keywords: dicarbonyl derived; coupling cyclic; derived iodonium; catalyzed coupling ... See more keywords