Visible-Light-Promoted Synthesis of 1,3-Dicarbonyl Sulfoxonium Ylides.
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DOI: 10.1021/acs.orglett.2c02346
Abstract: A novel visible-light-promoted coupling of diazoketones with sulfoxonium ylides, employing a violet light-emitting diode, is described under both batch and continuous flow conditions. This transformation permits the direct synthesis of synthetically useful 1,3-dicarbonyl sulfoxonium ylides… read more here.
Keywords: sulfoxonium; light promoted; synthesis; dicarbonyl sulfoxonium ... See more keywords