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Published in 2019 at "Theoretical Chemistry Accounts"
DOI: 10.1007/s00214-019-2434-1
Abstract: A thorough bonding analysis is performed on the dication [C6(CH3)6SO]2+. The results show that the molecule is best described in terms of covalent interactions between the cations C6(CH3)6+ and SO+, whereby the bonding consists of…
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Keywords:
bonding hexamethylbenzene;
hexamethylbenzene so2;
dication;
so2 dication ... See more keywords
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Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.02.019
Abstract: Abstract An acyclic flexible bis(α-iminopyridine) ligand has been employed for the stabilization of chlorostannyliumylidene and a tin(II) dication. The syntheses involve the abstraction of chloride from the tin dichloride precursor using trimethylsilyl trifluoromethane sulfonate. The…
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Keywords:
reactivity studies;
dication;
tin dication;
pyramidal tin ... See more keywords
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Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00597
Abstract: The formal two-electron reduction of the cyclo-tri(phosphonio)methanide dication 12+ results in a ring-opening reaction via C–P bond cleavage to yield the unique phosphanyl-functionalized carbodiphosphorane 2. In situ spectroelectrochemical investigations of the reduction of dication 12+…
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Keywords:
ring opening;
dication;
phosphonio methanide;
tri phosphonio ... See more keywords
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Published in 2019 at "ACS Omega"
DOI: 10.1021/acsomega.8b03192
Abstract: Syntheses and structures of anionic arylphosphate monoesters [ArOP(O)2(OH)]− (Ar = 2,6-CHPh2-4-R-C6H2; R = Me/Et/iPr/tBu) with different counter cations are reported. The counter cations were varied systematically: imidazolium cation, 2-methyl imidazolium cation, N-methyl imidazolium cation, N,N′-alkyl…
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Keywords:
cation;
dication;
imidazolium cation;
methyl imidazolium ... See more keywords
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Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c00493
Abstract: The synthesis and isolation of one of the few examples of a π-extended diamagnetic phenazine dication have been achieved by oxidizing a phenanthrene-based dihydrophenazine precursor. The resulting dication was isolated and fully characterized, highlighting an…
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Keywords:
phenanthrene;
dication;
dual reactivity;
reactivity ... See more keywords
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Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt04089g
Abstract: A short imidazolium based dication, with only three methylene units in the spacer linker, selectively directs the crystallization of zeolite HPM-12 (*UOE) as long as there is enough germanium present in the synthesis gel. The…
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Keywords:
zeolite;
dication;
charge;
hpm ... See more keywords
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Published in 2018 at "Physical Review A"
DOI: 10.1103/physreva.98.053430
Abstract: Author(s): Reedy, D; Williams, JB; Gaire, B; Gatton, A; Weller, M; Menssen, A; Bauer, T; Henrichs, K; Burzynski, P; Berry, B; Streeter, ZL; Sartor, J; Ben-Itzhak, I; Jahnke, T; Dorner, R; Weber, T; Landers, AL…
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Keywords:
dissociation;
dication;
double ionization;
photon double ... See more keywords