P(v) dications: carbon-based Lewis acid initiators for hydrodefluorination.
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DOI: 10.1039/c9cc04010b
Abstract: The P(iii) dication [(terpy)PPh]2+ is oxidized by reaction with o-chloranil or 9,10-phenanthrenequinone to give the P(v) dications [(terpy)(C6Cl4O2)PPh]2+ and [(terpy)(C14H8O2)PPh]2+, respectively. These species are coordinatively saturated at phosphorus and yet display the ability to effect… read more here.
Keywords: lewis acid; initiators hydrodefluorination; acid initiators; dications carbon ... See more keywords