Synthesis and Structural Analysis of (Imido)vanadium Dichloride Complexes Containing 2-(2′-Benz-imidazolyl)pyridine Ligands: Effect of Al Cocatalyst for Efficient Ethylene (Co)polymerization
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DOI: 10.1021/acsomega.7b01225
Abstract: (Imido)vanadium(V) dichloride complexes containing 2-(2′-benzimidazolyl)-6-methylpyridine ligand (L) of type V(NR)Cl2(L) [R = 1-adamantyl (Ad, 1), C6H5 (2), and 2,6-Me2C6H3 (3)] have been prepared, and their structures were determined by X-ray crystallography as distorted trigonal bipyramidal… read more here.
Keywords: vanadium dichloride; imido vanadium; ethylene polymerization; dichloride complexes ... See more keywords
Novel Cobalt Dichloride Complexes with Hindered Diphenylphosphine Ligands: Synthesis, Characterization, and Behavior in the Polymerization of Butadiene
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DOI: 10.3390/molecules24122308
Abstract: Two novel cobalt diphenylphosphine complexes were synthesized by reacting cobalt(II) chloride with tert-butyl(diphenyl)phosphine (PtBuPh2) and (S)-(+)neomenthyldiphenylphosphine [(S)-NMDPP]. The crystal structure of the former was determined by single-crystal X-ray diffraction studies. The two complexes were then… read more here.
Keywords: polymerization; novel cobalt; cobalt dichloride; butadiene ... See more keywords