Dichotomy of Atom-Economical Hydrogen-Free Reductive Amidation vs Exhaustive Reductive Amination.
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DOI: 10.1021/acs.orglett.7b02821
Abstract: Rh-catalyzed one-step reductive amidation of aldehydes has been developed. The protocol does not require an external hydrogen source and employs carbon monoxide as a deoxygenative agent. The direction of the reaction can be altered simply… read more here.
Keywords: dichotomy atom; economical hydrogen; atom economical; amidation ... See more keywords