具有 μ -OH, μ -O 2 双钴核结构的基于多吡啶配体的配合物催化水氧化反应的能力
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DOI: 10.1016/s1872-2067(17)62923-1
Abstract: Abstract Two polypyridine complexes containing μ-OH, μ-O2 dicobalt(III) cores, [(TPA)CoIII(μ-OH)(μ-O2) CoIII(TPA)](ClO4)3 and [(BPMEN)CoIII(μ-OH)(μ-O2)CoIII(BPMEN)](ClO4)3 (TPA = tris(2-pyridylmethyl)amine, BPMEN = N,N′-dimethyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine), have previously been reported as inactive in the light-driven water oxidation reaction (ACS Catal., 2016, 6,… read more here.
Keywords: dicobalt iii; water; driven water; water oxidation ... See more keywords