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1
Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b05722
Abstract: Pyrazolate-based μ-1,2-peroxo dicopper(II) complex 1 undergoes clean 1e- oxidation at low potential (-0.59 V vs Fc/Fc+) to yield the rather stable μ-1,2-superoxo dicopper(II) complex 3, which was characterized by spectroscopic methods (ν̃(O-O) = 1070 cm-1,…
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Keywords:
dicopper;
atom abstraction;
thermodynamics;
superoxo dicopper ... See more keywords
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2
Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00275b
Abstract: A density functional theory study was carried out to investigate the reduction mechanisms of NO to N2O using a dicopper complex reported by Zhang and coworkers (J. Am. Chem. Soc., 2019, 141, 10159-10164). The reaction…
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Keywords:
mechanistic study;
using dicopper;
reduction;
dicopper complex ... See more keywords
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1
Published in 2023 at "Molecules"
DOI: 10.3390/molecules28114487
Abstract: A challenge in mimicking tyrosinase activity using model compounds is to reproduce its enantioselectivity. Good enantioselection requires rigidity and a chiral center close to the active site. In this study, the synthesis of a new…
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Keywords:
copper;
sulfoxidation;
dicopper complex;
tyrosinase ... See more keywords