A cyanide-bridged one-dimensional CrIIICoII metamagnet based on the trans-dicyanidechromate(III) building block
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DOI: 10.1016/j.ica.2017.03.034
Abstract: Abstract A cyanide-bridged CrIIICoII bimetallic complex [Cr(bpb)(CN)2Co(LN5)·2H2O·ClO4]n (bpb2− = 1,2-bis(pyridine-2-carboxamido)benzenate, LN5 = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene) (1) has been synthesized by the reaction of [CoII(LN5)(H2O)2](ClO4)2 with the trans-dicyanidechromate(III) building block K[CrIII(bpb)(CN)2]. X-ray single crystal diffraction analysis shows that complex 1 exhibits a… read more here.
Keywords: dicyanidechromate iii; cyanide bridged; building block; trans dicyanidechromate ... See more keywords