A computational investigation of the selectivity and mechanism of the Lewis acid catalyzed oxa‐Diels–Alder cycloaddition of substituted diene with benzaldehyde
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26547
Abstract: The selectivity and the mechanism of the uncatalyzed and AlCl3 catalyzed hetero‐Diels–Alder reaction (HDR) between ([E]‐4‐methylpenta‐2,4‐dienyloxy)(tert‐butyl)dimethylsilane 1 and benzaldehyde 2 have been studied using density functional theory at the MPWB1K/6‐31G(d) level of theory. The uncatalyzed… read more here.
Keywords: lewis acid; diels alder; mechanism; diene benzaldehyde ... See more keywords