Regioselective synthesis of allylic/propargylic alcohols from conjugated dienes/enynes catalyzed by CuCl under aerobic conditions.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc05099e
Abstract: An effective method for the regioselective synthesis of allylic/propargylic alcohols from conjugated dienes/enynes with the CuCl/HBpin system under air is described herein. This reaction features mild conditions, excellent regioselectivity and broad substrate scope, as various… read more here.
Keywords: allylic propargylic; dienes enynes; propargylic alcohols; synthesis allylic ... See more keywords
Difunctionalization of Dienes, Enynes and Related Compounds via Sequential Radical Addition and Cyclization Reactions
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28031145
Abstract: Radical reactions are powerful in creating carbon–carbon and carbon–heteroatom bonds. Designing one-pot radical reactions with cascade transformations to assemble the cyclic skeletons with two new functional groups is both synthetically and operationally efficient. Summarized in… read more here.
Keywords: difunctionalization dienes; addition cyclization; dienes enynes; radical addition ... See more keywords