Asymmetric Assemblies of 1,3-Dienes, Sulfuric Diamide, and Aldehydes to Access 1,3-Diamines through Relay Amine/Palladium Catalysis.
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DOI: 10.1021/acs.orglett.2c03762
Abstract: A relay catalytic protocol using pyrrolidine and palladium catalysis has been developed for asymmetric synthesis of 1,3-diamine derivatives from 3-substituted 1,3-dienes, sulfuric diamide, and aldehydes. This one-pot, three-component reaction features the advantages of a high… read more here.
Keywords: dienes sulfuric; palladium catalysis; diamide aldehydes; sulfuric diamide ... See more keywords