Diethylzinc-Mediated Radical 1,2-Addition of Alkenes and Alkynes.
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DOI: 10.1021/acs.orglett.1c00669
Abstract: A novel diethylzinc-mediated radical 1,2-addition of perfluoroalkyl iodides to unactivated alkenes and alkynes is presented, which demonstrates a novel way to generate an ethyl difluoroacetate radical. This method is highly efficient and gives full conversions… read more here.
Keywords: addition alkenes; diethylzinc mediated; mediated radical; radical addition ... See more keywords