Selenium makes the difference: protonation of [FeFe]-hydrogenase mimics with diselenolato ligands.
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DOI: 10.1039/c7dt00057j
Abstract: The synthetic models of the active site of an [FeFe]-hydrogenase containing a Sn atom in the bridgehead of the diselenato ligand, namely [Fe2(CO)6{μ-(SeCH2Se)SnMe2}], 3 and [Fe2(CO)6{μ-(SeCH2)2SnMe2}], 4 have been synthesized and characterized by different spectroscopic… read more here.
Keywords: makes difference; fefe hydrogenase; difference protonation; hydrogenase ... See more keywords