Observation of different reactivities of para and ortho-water towards trapped diazenylium ions
Sign Up to like & getrecommendations! Published in 2018 at "Nature Communications"
DOI: 10.1038/s41467-018-04483-3
Abstract: Water is one of the most fundamental molecules in chemistry, biology and astrophysics. It exists as two distinct nuclear-spin isomers, para- and ortho-water, which do not interconvert in isolated molecules. The experimental challenges in preparing… read more here.
Keywords: trapped diazenylium; diazenylium ions; ortho water; water ... See more keywords
Theoretical investigation of different reactivities of Fe(IV)O and Ru(IV)O complexes with the same ligand topology
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2016.1277023
Abstract: Abstract The structures and mechanisms for hydrogen abstraction from isopropylbenzene for four high-valence complexes, cis-β-[FeIV(O)(BQCN)]2+ (Fe-2b and Fe-2b-2) and cis-β-[RuIV(O)(BQCN)]2+ (Ru-2b and Ru-2b-2) (BQCN = N,N′-dimethyl-N,N′-bis(8-quinolyl)-cyclohexanediamine), were investigated using density functional theory. Of the two… read more here.
Keywords: topology; reactivity; theoretical investigation; investigation different ... See more keywords