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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01445
Abstract: The nucleophilic reactivity of α,α-difluorinated gem-diols toward activated pyridinium salts has been capitalized in a highly regioselective fashion, offering biologically relevant 1,4-dihydropyridines and 3,4-dihydro-2-pyridones adorned with the valuable gem-difluoromethylene motif. The protocol is scalable as…
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Keywords:
gem;
divergent reaction;
gem diols;
reaction activated ... See more keywords