Access to cyclic gem-difluoroacyl scaffolds via electrochemical and visible light photocatalytic radical tandem cyclization of heteroaryl chlorodifluoromethyl ketones.
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DOI: 10.1039/c7cc02979a
Abstract: A variety of unprecedented scaffolds containing a difluoroacyl moiety were obtained in moderate to good yields, with excellent diastereoselectivity, via electrochemical or photochemical activation of difluoroacyl heteroaryles with a series of olefinic substrates. read more here.
Keywords: difluoroacyl; access cyclic; difluoroacyl scaffolds; cyclic gem ... See more keywords