Highly Enantioselective Desymmetrization of Centrosymmetric pseudo-para-Diformyl[2.2]paracyclophane via Asymmetric Transfer Hydrogenation
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DOI: 10.1021/acscatal.8b01872
Abstract: Herein we describe the desymmetrization of a centrosymmetric pseudo-para-diformyl[2.2]paracyclophane based on Noyori asymmetric transfer hydrogenations (ATH). The reduction proceeds smoothly in the presence of commercially available ruthenium complexes to afford a monohydroxymethylated product in good… read more here.
Keywords: pseudo para; desymmetrization centrosymmetric; para diformyl; centrosymmetric pseudo ... See more keywords