Application of Sulfur Ylides in 1,2-Difunctionalization of Arynes via Insertion into a C-S σ-Bond.
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DOI: 10.1021/acs.orglett.7b04003
Abstract: A novel reactivity of sulfur ylides has been demonstrated in a transition-metal-free protocol to access ortho-substituted thioanisole derivatives by insertion of arynes into a C-S σ-bond in moderate to good yields. The reaction involves the… read more here.
Keywords: application sulfur; ylides difunctionalization; sulfur ylides; insertion ... See more keywords